As of version 0.95.0, Enigmail relies by default on GnuPG for selecting the hash (digest) algorithm. From GnuPG, the hash algorithm can be specified in the file gpg.conf using the parameter digest-algo hash_algorithm.
If you want to select the hash algorithm from within Enigmail, you can do so by modifying the preference extensions.enigmail.mimeHashAlgorithm and assigning to it one of the following values:
0 – automatic selection, let GnuPG choose
1 – SHA1
2 – RIPEMD160
3 – SHA256
4 – SHA384
5 – SHA512
To know more about modifying the preference values manually, also read Section 9.2.